I.V. Kuraieva. PECULIARITIES OF Pb, Mo, Cu AND Zn DISTRIBUTION IN WATER OF ARTESIAN AQUIFERS (WITHIN KYIV DEPOSIT)

https://doi.org/10.15407/mineraljournal.42.02.063

UDC 550.4:556.3:502/504 (477)

PECULIARITIES OF Pb, Mo, Cu AND Zn DISTRIBUTION IN WATER OF ARTESIAN AQUIFERS (WITHIN KYIV DEPOSIT)

I.V. Kuraieva, DrSc (Geology), Prof., Head of Department.

M.P. Semenenko Institute of Geochemistry,

Mineralogy and Ore Formation of the NAS of Ukraine

34, Acad. Palladin Ave., Kyiv, Ukraine, 03142

E-mail: KI4412674@gmail.com

https://orcid.org/0000-0003-3113-7782

T.O. Koshliakova, PhD (Geology), Senior Research Fellow.

M.P. Semenenko Institute of Geochemistry,

Mineralogy and Ore Formation of the NAS of Ukraine

34, Acad. Palladin Ave., Kyiv, Ukraine, 03142

E-mail: geol@bigmir.net

https://orcid.org/0000-0001-8551-3531

K.S. Zlobina, PhD (Geology), Research Fellow.

M.P. Semenenko Institute of Geochemistry,

Mineralogy and Ore Formation of the NAS of Ukraine

34, Acad. Palladin Ave., Kyiv, Ukraine, 03142

E-mail: ecaterinka@ukr.net

https://orcid.org/0000-0001-8823-4642

Language: Ukrainian

Mineralogical journal 2020, 42 (2): 63-73

Abstract:

In the article, the authors present their own results of the study of hydrogeochemical peculiarities of distribution of leading ecological-forming microelements (Pb, Mo, Cu and Zn) in potable artesian aquifers of Kyiv groundwater field. A comparative analysis of the values of maximum permissible concentrations (MPC) of the main macro- and microcoelements for potable groundwater in accordance with domestic and foreign regulatory documents was done. It was concluded that the most stringent as to the content of macroelements are the requirements of the World Health Organization, and as to the content of microelements are domestic standards, namely the Sanitary Rules (SanPiN 2.2.4-171-10). By use of statistical methods, the authors analised the investigated microelements in groundwater timed to Cenomanian-Callovian groundwater complex and Bajocian aquifer. As a result of the research the MPC excess for lead was established in single wells. In addition, it was found that the average concentrations of microelements in Bajocian aquifer are higher than that of Cenomanian-Callovian complex. It was suggested that the natural (lithological composition of the water-bearing stratum) and technogenic (aeration zone pollution by heavy metals, confining bed pinching out along the Dnieper River, hydrodynamic flow inversion) factors are mutually reinforcing, which affects the content of these trace elements in deep aquifers of the Dnieper-Donetsk artesian basin. The authors emphasize the need for further research aimed at establishing patterns of distribution and forms of migration of micro- and ultramicroelements in groundwater by use of thermodynamic modeling method.

Keywords: groundwater, ecological-forming microelements, maximum permissible concentration, environmental hydrogeochemistry, heavy metals, Kyiv deposit.

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