UNUSUAL ASSOCIATIONS OF NATIVE METALS IN THE PLATOBASALTS OF VOLYN AND CONDITIONS OF THEIR FORMATION

UDC 553.2

https://doi.org/10.15407/mineraljournal.38.04.014

I.M. Mysiak, L.Z. Skakun, R.Ya. Serkiz
Ivan Franko Lviv National University
4, Hryshevsky Str., Lviv, Ukraine, 79005
E-mail: mysiak10@gmail.com
UNUSUAL ASSOCIATIONS OF NATIVE METALS IN THE PLATOBASALTS OF VOLYN AND CONDITIONS OF THEIR FORMATION
Language: Ukrainian
Mineralogical journal 2016, 38 (4): 14-22

Abstract: Here we present the results of investigations of native Al, Sn, Fe, stanum and iron chlorides, compounds FeSiAl and FeCrNiTi, which have been found in situ in the basalts of Ratno beds of Volyn series. Hydrothermally altered basalts with calcite-zeolite-quartz mineralization serve as the object. The mineral phases have been found in the fissures that cross zones of development of the zeolite-calcite-quartz mineralization with native Cu and Ag. Results. Native metals and compounds which have been identified form two associations. Association I is formed by Cu and Ag paragenesis in the zone of zeolitecalcite-quartz mineralization. Association II is presented by native Fe, Sn, Al, stanum and iron chlorides, iron silicide, alloy FeCrNiTi, which have been found in the fissures that cross zone of the zeolite-calcite-quartz mineralization. Discussion. Association I is a product of hydrothermal systems in platobasalts. Association II was formed without water as a result of condensation of gas that moved through fissures of rock. The presence of stanum and iron chlorides is a proof of that the association Fe, Sn, Al, FeCrNiTi, FeSi was formed from gas flows. Conclusions. Native metals and compounds which have been identified belong to the two associations of different ages. Early association (native Cu, Ag) was formed as the product of the hydrothermal systems in platobasalts. Late association (native Fe, Sn, Al, iron silicide, and ferric chloride, stanum and iron silicide, natural alloy FeCrNiTi) was formed in pneumatolytic system which probably was associated with gas flows that accompanied the formation of Devonian rift system.

Keywords: native metals, copper, silver, iron, tin, aluminum, stanum and iron chloride, natural alloy FeCrNiTi.

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