N.O. Kryuchenko. GEOCHEMISTRY OF SOIL OF NARCISSUS VALLEY AND SPIVAKOVE TRACT (TRANSCARPATHIA)

English

https://doi.org/10.15407/mineraljournal.41.04.050

UDC 550.42 (477.87)

GEOCHEMISTRY OF SOIL OF NARCISSUS VALLEY AND SPIVAKOVE TRACT (TRANSCARPATHIA)

N.O. Kryuchenko 1, https://orcid.org/0000-0001-8774-9089

E.Ya. Zhovinsky 1, https://orcid.org/0000-0003-1601-5998

P.S. Paparyha 2 

1 M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of Ukraine

34, Acad. Palladin Ave., Kyiv, Ukraine, 03142

E-mail: nataliya.kryuchenko@gmail.com, zhovinsky@ukr.net

2 Carpathian Biosphere Reserve of the Ministry of Environmental Protection of Ukraine

77, Red Pleso Str., Rakhiv, Ukraine, 90600

E-mail: paparyga@ukr.net

Language: Ukrainian

Mineralogical journal 2019, 41 (4): 50-60

Abstract:

Geochemical studies of ecosystems of the narrow-leaved narcissus (Narcissus angustifolius subsp. Radiiflorus, hereinafter as N. angustifolius) of the protected areas of the Carpathian biosphere reserve - the Narcissus Valley of (plain part) and the Spivakove tract (low mountains) are carried out for the first time. The trace element composition (Li, Be, Al, Cd, Sb, V, Cr, Fe, Mn, Ni, Cu, Zn, Mo, Ag, Hg, Sr, Co, As, Sn, Se, Rb, Nb, Cs, Ba, Pb, Bi, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) of soils and parts of N. angustifolius (roots, bulbs, leaves, flowers) is determined by ICP-MS. The series of biological absorption of the chemical elements by N. angustifolius are compiled. Which results in distinguishing groups of elements - biologically accumulated (Mn, Cu, Zn, Mo, Cd, Hg, Sn, Sb, Sr, Rb) and biologically captured by various parts of N. angustifolius. For the Narcissus Valley a maximum value of trace elements accumulation are registered in the roots and leaves N. angustifolius, with Spivakove tract these values are typical of flowers. Comparisons of data obtained for N. angustifolius makes it possible distinguish the group of elements of energetic accumulation: Narcissus Valley massif - Sn, Cd, Sb, Spivakove tract - Sn, Sr, Zn, Rb. The income of each element in N. angustifolius was analyzed and their necessity for the existence of ecosystems is established. Based on an analysis of chemical composition of soil and rock, and N. angustifolius as well, it is supposed that their growth should be caused by the presence of effusive rocks (andesites, basalts and tuffs) and brown, loamy earth soils.

Keywords: environmental geochemistry, narrow-leaved narcissus (N. angustifolius), Narcissus Valley of massif, Spivakove tract, microelement composition, biological accumulation and capture.

References:

  1. Avessalomova, I.A. (1978), Geohimicheskie pokazateli pri izuchenii landshaftov, Moskovskiy gos. un-t, Moskow, RU, 108 p. [in Russian].
  2. Voloshchuk, M.І., Gleb, R.Yu., Kabal, M.V. and Suharyuk, D.D. (2017), Priroda Karpat, No. 1, Rahiv, UA, pp. 28-36 [in Ukrainian].
  3. Gabinet, M.P., Kulchitskii, Ya.O. and Matkovskii, O.I. (1976), Geologiia i poleznye iskopaemye Ukrainskikh Karpat, Vyshcha shkola, Ch. 1. Lvov, UA, 200 p. [in Russian].
  4. Golyshin, N.M. (1993), Fungicidy, Kolos, Moscow, RU, 319 p. [in Russian].
  5. Dushenkov, V. and Raskin, I. (1999), Himiya i zhyzn - XXI vek, Vol. 11, Nauka, Moscow, RU, pp. 48-49 [in Russian].
  6. Lozinyak, P. and Mіsyura, Y.A. (2010), Geologіya і geohіmіya goryuchyh kopalyn, No. 3-4 (152-153), Lviv, UA, pp. 73-84 [in Ukrainian].
  7. Rudenko, L.G. (ed.) (2007), Nacіonalniy atlas Ukrainy, DNVP Kartografіya, Kyiv, UA, 440 p. [in Ukrainian].
  8. Perelman, A.I. (1979), Geohimiya, Vysshaia shkola, Moscow, RU, 423 p. [in Russian].
  9. Pokinchereda, V.F., Voloshchuk, M.І., Pіpash, L.І. and Paparyga, P.S. (2016), Priroda Karpat, No. 1, Rahiv, UA, pp. 73-83 [in Ukrainian].
  10. Pop, S.S. (2003), Pryrodnі resursy Zakarpattya, Uzhgorodskiy Nac. Univ., Uzhgorod, UA, 296 p. [in Ukrainian].
  11. Gerenchuk, K.І. (eds) (1981), Pryroda Zakarpatskoiy oblastі, Lviv. Univ., Lviv, UA, 156 p. [in Ukrainian].
  12. Nikolskii, B.V. (ed.) (1966), Spravochnik khimika, Khimiia, Moscow, RU, 1072 p. [in Russian].
  13. Sushchik, Yu.Ya. (1978), Geohimiya zony gipergeneza Ukrainskih Karpat, Naukova dumka, Kyiv, UA, 210 p. [in Russian].
  14. Ustimenko, P.M., Dubina, D.V. and Gamor, F.D. (2007), Ukrainskiy botanіchniy zhurnal, Vol. 64, No. 2. Kyiv, UA, pp. 195-205 [in Ukrainian].
  15. Shcherbakov, A.P. and Rudaj, I.D. (1983), Plodorodie pochv, krugovorot i balans pitatelnyh veshchestv, Kolos, Moscow, RU, 189 p. [in Russian].
  16. Kricsfalusi, V.V. and Komendar, V.I. (1985), Tiscia an ecological journal. University of Szeged, Hungary, 20, pp. 99-110.
  17. Zhovinsky, E.Ya., Kryuchenko, N.O. and Paparyha, P.S. (2013), Geochemistry of environmental objects of the Carpathian biosphere reserve, Nac. acad. of Sci. of Ukraine, M.P. Semenenko Inst. of geochemistry, mineralogy and ore formation, Kyiv, UA, 100 p.

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