D.A. Yaroshchuk, LITHIUM IN THE SUBSOIL OF UKRAINE Part 10. Lithium-bearing objects genesis: Ukrainian Shield rare-metal pegmatites
https://doi.org/10.15407/mineraljournal.47.02.020
UDC 549.553.34 (477)
LITHIUM IN THE SUBSOIL OF UKRAINE
Part 10. Lithium-bearing objects genesis: Ukrainian Shield rare-metal pegmatites
D.A. Yaroshchuk, Graduate Student
E-mail: mitya.yaroshchuk@gmail.com; orcid: 0000-0003-0190-8611
V.I. Pavlyshyn, DrSc (Geology, Mineralogy), Prof.,
Academician of the AS Higher School of Ukraine, Head of Department
E-mail: V.I.Pavlyshyn@gmail.com; ResearcherID: D-6558-2019
I.M. Lunova, PhD (Geology), Research Fellow
E-mail: gerasimetsirina@gmail.com; orcid: 0000-0003-4670-0216
M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of Ukraine
34, Acad. Palladin Ave., Kyiv, Ukraine, 03142
Language: Ukrainian
Mineralogical journal 2025, 47 (2): 20-32
Abstract: Ukrainian Shield rare-metal pegmatites genesis correlation in accordance with their types is made — spodumene, spodumene-petalite, petalite. Ukrainian Shield spodumene pegmatites (Kryvyi Rih, Azov) are considered as magmatic formations with a necessarily developed post-magmatic stage, often productive. Shevchenkivske deposit spodumene-petalite pegmatites have had a more complicated history, since it was formed in tectonically turbulent conditions. A spodumene-I formation as a result of petalite crystal structure solid-state transformation and decomposition into spodumene-I and quartz hypothesis substantiated. Petalite pegmatites of Inhul megablock (in our terminology — metapegmatites) formation had occurred during two stages — magmatic and metasomatic. The possible time gap between the stages is the first hundreds of millions of years. Fine-grained quartz-albite-petalite rock — the main ore of pegmatites — had formed as a result of spodumene pegmatites minerals metasomatic replacement. Abyssal CO2 fluids flows had provoked and carried out the alteration process. On the lithium minerals phase diagram CO2 isochores with a density of 0.88—0.89 g/cm3 in the petalite field are characterized by values close to the PT parameters of the triple point "petalite — spodumene — β-spodumene" — 680 °C and 410 MPa.
Keywords: petalite pegmatites, genesis of rare-metal pegmatites, structural state of feldspars, pegmatite magma, metasomatism, quartz-albite-petalite rock, CO2-abyssal flows, solid-state alteration.
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