M.M. Reshetnyk, PETROCHRONOLOGY OF GRANITOIDS (SOBITES) IN THE ROS-TIKYCH AND DNIESTER-BOUH DOMAINS JUNCTION ZONE, THE UKRAINIAN SHIELD

https://doi.org/10.15407/mineraljournal.47.03.055

UDC 550.93

PETROCHRONOLOGY OF GRANITOIDS (SOBITES) IN THE ROS-TIKYCH AND

DNIESTER-BOUH DOMAINS JUNCTION ZONE, THE UKRAINIAN SHIELD

M.M. Reshetnyk 1, 9, PhD,, Senior Researcher

E-mail: reshetnykmariya@gmail.com; orcid: 0000-0002-5067-7728

L.V. Shumlyanskyy 2—4, DrSc,, Professor

E-mail: lshumlyanskyy@yahoo.com; orcid: 0000-0002-6775-4419

D. Chew 5, Professor

E-mail: chewd@tcd.ie; orcid: 0000-0002-6940-1035 

B. Dhuime 6, PhD

E-mail: bruno.dhuime@umontpellier.fr; orcid: 0000-0002-4146-4739

A. Wudarska 2, 7, DrSc, Associate Professor

E-mail: ndgiera@cyf-kr.edu.pl; orcid: 0000-0001-9802-5107

D.L. Starokadomsky 3, 8, PhD

E-mail: km80@ukr.net; orcid: 0000-0001-7361-663X

1 National Museum of Natural History of the NAS of Ukraine, Kyiv, Ukraine

2 Institute of Geological Sciences of the Polish Academy of Sciences, Warsaw, Poland

3 M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of Ukraine, Kyiv, Ukraine

4 Curtin University, Perth, Australia

5 Trinity College, School of Natural Sciences, Department of Geology, Dublin, Ireland

6 Géosciences Montpellier, Université de Montpellier, France

7 GFZ Helmholtz Centre for Geosciences, Telegrafenberg, 14473 Potsdam, Germany

8 Chuiko Institute of Surface Chemistry of the NAS of Ukraine, Kyiv, Ukraine

9 Taras Shevchenko National University of Kyiv, Kyiv, Ukraine

Language: Ukrainian

Mineralogical journal 2025, 47 (3): 55-68

Abstract: An isotopic-geochronological and geochemical study of zircon and fluorapatite was conducted on Paleoproterozoic granitoids from the Ros-Tikych Domain in the south-western part of the Ukrainian Shield. Granitoids of three age populations (ca. 3.8, 3.0-2.8, and 2.1-2.0 Ga) are widely distributed in the Middle Bouh area, which includes the southern part of the Ros-Tikych Domain. This study aimed to clarify the origin of the Paleoproterozoic granitoids. Using the U-Pb dating method, new data were obtained regarding the formation time of charnockitoids (so-called "sobites") in the Haisyn block. Zircon from two-pyroxene diorite yielded an upper intercept age of 2087±16 Ma (a single inherited crystal yielded an age of 3174±13 Ma). Fluorapatite from diorite and monzosyenite yielded a U-Pb age of 1451±110 Ma. The hafnium isotopic composition in zircon from two-pyroxene diorite has a negative weighted average εHf of –4.3±0.8. According to the felsic crust model (176Lu/177Hf = 0.010), the model age is ca. 2800 Ma; for the inherited crystal, it is ca. 3800 Ma. The oxygen isotope ratios (δ18OVSMOW values) in fluorapatite range from 5.1 to 6.1 ‰, with a mean value of 5.6±0.3 ‰ (1 standard deviation). This corresponds to the mantle values characteristic of tonalite-trondhjemite-granodiorite (TTG) associations. The data suggest that the Paleoproterozoic charnockitoids formed as a result of melting the Meso-Neoarchean lower continental crust. After crystallisation, these rocks underwent slow cooling and exhumation from 800-750 °С at ca. 2.1 Ga to 500-400 °С at ca. 1.4 Ga.

Keywords: petrochronology, charnockite, Paleoproterozoic, Ukrainian Shield, fluorapatite.

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