M.M. Reshetnyk, CHEMICAL AND ISOTOPIC COMPOSITION OF FLUOR-APATITES FROM INTERMEDIATE IGNEOUS ROCKS OF THE HAISYN BLOCK OF THE UKRAINIAN SHIELD: EVIDENCE OF THE HETEROGENEITY OF THE PRIMARY MELTS
https://doi.org/10.15407/mineraljournal.47.04.025
UDC 550.93
CHEMICAL AND ISOTOPIC COMPOSITION OF FLUOR-APATITES
FROM INTERMEDIATE IGNEOUS ROCKS OF THE HAISYN BLOCK OF THE UKRAINIAN
SHIELD: EVIDENCE OF THE HETEROGENEITY OF THE PRIMARY MELTS
M.M. Reshetnyk 1, PhD, Senior Researcher
E-mail: reshetnykmariya@gmail.com; orcid: 0000-0002-5067-7728
L.V. Shumlyanskyy 2—4, DrSc, Professor
E-mail: lshumlyanskyy@yahoo.com; orcid: 0000-0002-6775-4419
B. Marciniak-Maliszewska 5, Dr.
E-mail: b.maliszewska@uw.edu.pl; orcid: 0000-0001-9147-6693
P. Jokubauskas 5, Dr.
E-mail: p.jokubauskas@uw.edu.pl; orcid: 0000-0002-1099-4497
B. Bagiński 5, Professor
E-mail: b.baginski1@uw.edu.pl; orcid: 0000-0002-5809-3452
B. Dhuime 6, PhD
E-mail: bruno.dhuime@umontpellier.fr; orcid: 0000-0002-4146-4739
A. Gumsley 2, Dr.
E-mail: anna.salacinska@twarda.pan.pl; orcid: 0000-0002-0889-3435
D.L. Starokadomsky 3, 7, PhD, Senior Researcher
E-mail: km80@ukr.net; orcid: 0000-0001-7361-663X
1 National Museum of Natural History of the NAS of Ukraine, Kyiv
2 Institute of Geological Sciences of the Polish Academy of Sciences, Warsaw, Poland
3 M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of Ukraine, Kyiv
4 Curtin University, Perth, Australia
5 Faculty of Geology, University of Warsaw, Warsaw, Poland
6 Géosciences Montpellier, Université de Montpellier, Montpellier, France
7 Chuiko Institute of Surface Chemistry of the NAS of Ukraine, Kyiv
8 Taras Shevchenko National University of Kyiv, Ukraine
Language: Ukrainian
Mineralogical journal 2025, 47 (4): 25-37
Abstract: The article investigates fluor-apatite from intermediate igneous rocks of the so-called "sobite" association of the Haisyn Complex in the Ros-Tikych Domain of the Ukrainian Shield. The chemical composition of fluor-apatite, the Sr isotopic composition and the mineral inclusions were examined. In terms of chemical composition, apatites closely resemble stoichiometric fluor-apatite. A significant negative Eu anomaly and the REE pattern are characteristic of apatite from high-Al (peraluminous) granites. On average, the LREE content in fluor-apatite from diorite is higher than that from monzonite. In contrast, the latter contains more Cl, V, Mn, Y, as well as MREE and HREE. Apatite contains numerous mineral inclusions: quartz, amphibole, biotite, K-feldspar, plagioclase, monazite, carbonates, magnetite and graphite. According to the amphibole-plagioclase thermobarometer, the crystallisation temperature of inclusions ranges from 735 to 790 ℃, with a pressure of ca. 2 kbar. Apatite from diorite exhibits a relatively constant Sr isotopic composition of 87Sr/86Sr = 0.71027 ± 0.00047, whereas apatite from monzonite shows significant variations in the 87Sr/86Sr ratio, with an average value of 0.71369 ± 0.00031. The studied rocks are highly complex, exhibiting features of both peraluminous granitoids and those belonging to the tonalite-trondhjemite-granodiorite association. Fluor-apatites and their inclusions crystallised from the melt, which contained fluid components, primarily water and carbon dioxide. There was a lack of isotopic equilibrium between the melts from which the studied monzonites and diorites crystallized; the diorite melt contained slightly more juvenile components, while the monzonite melt was predominantly a product of the melting of the ancient continental crust.
Keywords: fluor-apatite, REE, Ukrainian Shield, TTG association, diorite, monzonite.
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